A chemical ghost from a lost world
In the remote, ice-scoured terrain of southwestern Greenland lies the Isua Supracrustal Belt (also called the Isua Greenstone Belt), a formation containing some of the oldest preserved rocks on Earth. These rocks, dating back 3.7 to 3.8 billion years, hold a chemical signature that changes our understanding of Earth's formation. They contain a peculiar excess of an isotope called tungsten-182 (¹⁸²W). This anomaly shows the planet's violent beginnings, a time before the Earth we know today had fully formed.
The story of this anomaly begins with another element, hafnium-182 (¹⁸²Hf). This radioactive isotope, forged in supernovae before our solar system existed, decays into tungsten-182 with a half-life of only about 9 million years. This is extremely short in geological terms, meaning all primordial ¹⁸²Hf decayed into ¹⁸²W within the first 60 million years of the solar system's history. During Earth's formation, hafnium preferred to stay in the rocky, silicate mantle, while tungsten was drawn to the planet's iron core as it separated. The timing of this core formation relative to the decay of ¹⁸²Hf is what makes the tungsten isotope ratio a powerful planetary clock.